【文献推荐】以气凝胶为催化剂载体光分解水

研究人员在未使用交联剂的情况下通过自组装制备得到CN气凝胶,并且使用高比表面积的气凝胶作为催化剂载体光分解水,效果显著。参考文献:

气凝胶催化剂

Honghui Ou et al. Carbon Nitride Aerogels for the Photoredox Conversion of Water, Angewandte Chemie International Edition (2017). DOI: 10.1002/anie.201705926

Abstract

Aerogel structures have attracted increasing research interest in energy storage and conversion owing to their unique structural features, and a variety of materials have been engineered into aerogels, including carbon-based materials, metal oxides, linear polymers and even metal chalcogenides. However, manufacture of aerogels from nitride-based materials, particularly the emerging light-weight carbon nitride (CN) semiconductors is rarely reported. Here, we develop a facile method based on self-assembly to produce self-supported CN aerogels, without using any cross-linking agents. The combination of large surface area, incorporated functional groups and three-dimensional (3D) network structure, endows the resulting freestanding aerogels with high photocatalytic activity for hydrogen evolution and H2O2 production under visible light irradiation. This work presents a simple colloid chemistry strategy to construct 3D CN aerogel networks that shows great potential for solar-to-chemical energy conversion by artificial photosynthesis.

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